Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. , Product Details of 607-81-8, 607-81-8, Name is Diethyl benzylmalonate, molecular formula is C14H18O4, belongs to thiomorpholine compound. In a document, author is Ajibade, Peter A., introduce the new discover.
Synthesis and crystal structure of bis(thiomorpholinyldithiocarbamato) Zn(II): structural, optical, and photocatalytic studies of ZnS nanoparticles from the complex
Bis(thiomorpholinyldithiocarbamato) Zn(II) complex was synthesized and characterized by single crystal X-ray crystallography and spectroscopic techniques. The molecular structure of the compound revealed a dimeric Zn(II) complex in which each Zn(II) ion is bound to one chelating and two bridging thiomorpholine ligands. The compound was thermolyzed at 130 degrees C in octadecylamine (ODA), hexadecylamine (HDA), and oleylamine (OLA) to prepare ZnS nanoparticles. Powder X-ray diffraction (PXRD) of the ZnS nanoparticles indicates mixtures of hexagonal and cubic crystalline phases depending on thermolysis temperature. HRTEM micrographs showed well-defined nanoparticles with particle size of 3.3-4.8 nm for ODA-ZnS, 2.5-4.2 nm for OLA-ZnS, while HDA-ZnS shows slightly bigger nanoparticles with particle size of 3.3-5.4 nm. Estimated optical band gaps are 3.58 eV for ODA-ZnS, 3.69 eV for HDA-ZnS and 3.72 eV for OLA-ZnS which indicate blue shift of the absorption band edges with respect to bulk ZnS (3.56 eV). The as-prepared ZnS nanoparticles were used as photocatalysts for the degradation of methylene blue dye. The degradation efficiency of the as-prepared ZnS nanoparticles are 58% for ODA-ZnS, 53% for OLA-ZnS, and 43% for HDA-ZnS. ODA-ZnS nanoparticles were used for the recycling test and showed good photostability and recyclability with 57% recovery percentage.
A reaction mechanism is the microscopic path by which reactants are transformed into products. Each step is an elementary reaction. In my other articles, you can also check out more blogs about 607-81-8. Product Details of 607-81-8.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem