Chemistry can be defined as the study of matter and the changes it undergoes. You¡¯ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology. 100-21-0, Name is Terephthalic acid, molecular formula is , belongs to thiomorpholine compound. In a document, author is Jones, C, Formula: C8H6O4.
Alane- and gallane-sulfur donor chemistry: Synthesis of AlH3 center dot NMe(CH2CH2)(2)S, {AlH2[mu-N(CH2CH2)(2)S]}(2) and MH(SCH(2)CH(2)NEt(2))(2) (M=Al or Ga)
Reaction of N-methylthiomorpholine hydroiodide with LiAlH4 in OEt(2) yielded the Lewis-base adduct of alane, AlH3 . NMe(CH2CH2)(2)S 1, which is monomeric in benzene as the N-donor species. Thiomorpholine with H3Al . NMe(3) also in OEt(2) afforded the metallated species {AlH2[mu-N(CH2CH2)(2)S]}(2) 2; in the solid-state dimers arising from bridging amido centres are weakly associated via intermolecular Al … S interactions at 3.22(3) Angstrom. Treatment of 2-diethylaminoethanethiol hydrochloride with LiMH(4) (M = Al or Ga) in OEt(2) or tetrahydrofuran generated the five-co-ordinate species MH(SCH(2)CH(2)NEt(2))(2) (M = Al 3 or Ga 4), authenticated by X-ray crystallography as isostructural, chiral five-co-ordinate species in the solid, the N-donor groups occupying apical positions of trigonal-bipyramidal metal centres.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 100-21-0, in my other articles. Formula: C8H6O4.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem