Chemistry is an experimental science, Recommanded Product: 102-06-7, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 102-06-7, Name is 1,3-Diphenylguanidine, molecular formula is C13H13N3, belongs to thiomorpholine compound. In a document, author is Martynov, A. V..
Synthesis of new heterocycles by oxidation of functionalized cyclic derivatives of bis(2-chlorovinyl) sulfide and selenide
Oxidation of 4-substituted 2,6-bis[(E)-chloromethylidene]thiomorpholine with hydrogen peroxide in a mixture of chloroform with acetic acid afforded the corresponding 4-R-2,6-bis[(E)-chloromethylidene]-thiomorpholine 1-oxide. The results of oxidation of bis[(E)-chloromethylidene]-1,4-dichalcogenanes under analogous conditions depended on the chalcogen nature and its position in the ring. The reaction of 2,6-bis[(E)-chloromethylidene]-1,4-dithiane gave 2,6-bis[(E)-chloromethylidene]-1,4-dithiane-1,1,4,4-tetraone, whereas 3,5-bis[(E)-chloromethylidene]-1,4-thiaselenane-1,1-dione was unexpectedly obtained from 3,5-bis[(E)-chloromethylidene]-1,4-thiaselenane. 2,6-Bis[(E)-chloromethylidene]-1,4-thiaselenane and 2,6-bis[(E)-chloromethylidene]-1,4-diselenane decomposed under the oxidation conditions.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 102-06-7, in my other articles. Recommanded Product: 102-06-7.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem