Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 135-02-4, Name is 2-Methoxybenzaldehyde, molecular formula is C8H8O2. In an article, author is Schwan, Adrian L.,once mentioned of 135-02-4, Computed Properties of C8H8O2.
Origins and applications of stereoselective sulfenate anion alkylation reactions
Selected sulfenate anions can be alkylated with diastereoselectivities near 9:1 when there is appropriately positioned carbon chirality in the sulfenate structure or in the alkylation electrophile. Both protocols represent a conceptually different approach to beta-amino sulfoxides. When vinylic beta-amino sulfoxides are cyclized, thiomorpholine S-oxides result, and substrate control over the stereochemistry of alkyl substituents was found. This finding facilitates the synthesis of cis and trans dialkylpyrrolidines, known ant venom alkaloids. A computational model is demonstrated to account for some of the diastereoselection results. The importance of intramolecular interactions of sulfenate constituent atoms with pendent substituents is established.
If you¡¯re interested in learning more about 135-02-4. The above is the message from the blog manager. Computed Properties of C8H8O2.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem