Related Products of 88-68-6, Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. 88-68-6, Name is 2-Aminobenzamide, SMILES is O=C(N)C1=CC=CC=C1N, belongs to thiomorpholine compound. In a article, author is Conway, William, introduce new discover of the category.
Toward Rational Design of Amine Solutions for PCC Applications: The Kinetics of the Reaction of CO2(aq) with Cyclic and Secondary Amines in Aqueous Solution
The kinetics of the fast reversible carbamate formation reaction of CO2(aq) with a series of substituted cyclic secondary amines as well as the noncyclic secondary amine diethanolamine (DEA) has been investigated using the stopped-flow spectrophotometric technique at 25.0 degrees C. The kinetics of the slow parallel reversible reaction between HCO3- and amine has also been determined for a number of the amines by H-1 NMR spectroscopy at 25.0 degrees C. The rate of the reversible reactions and the equilibrium constants for the formation of carbamic acid/carbamate from the reactions of CO2 and HCO3- with the amines are reported. In terms of the forward reaction of CO2(aq) with amine, the order with increasing rate constants is as follows: diethanolamine D EA) < morpholine (MORP) similar to thiomorpholine (TMORP) < N-methylpiperazine (N-MPIPZ) < 4-piperidinemethanol (4-PIPDM) similar to piperidine (PIPD) < pyrrolidine (PYR). Both 2-piperidinemethanol (2-PIPDM) and 2-piperidineethanol (2-PIPDE) do not form carbamates. For the carbamate forming amines a Bronsted correlation relating the protonation constant of the amine to the carbamic acid formation rate and equilibrium constants at 25.0 degrees C has been established. The overall suitability of an amine for PCC in terms of kinetics and energy is discussed. Related Products of 88-68-6, Each elementary reaction can be described in terms of its molecularity, the number of molecules that collide in that step. The slowest step in a reaction mechanism is the rate-determining step.you can also check out more blogs about 88-68-6.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem