Related Products of 100-13-0, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 100-13-0, Name is 1-Nitro-4-vinylbenzene, SMILES is C=CC1=CC=C([N+]([O-])=O)C=C1, belongs to thiomorpholine compound. In a article, author is Arca, M, introduce new discover of the category.
Interaction of morpholine and thiomorpholine with molecular diiodine: X-ray crystal structure of morpholinium triiodide
The reactions between the donors morpholine (1) and thiomorpholine (2) with I-2 in low polar solvents (C6H6, CHCl3, CH2Cl2) and different donor/I-2 concentration ratios (1:1, 1:2, 1:3) yield solids of stoichiometry 1 . I-2, 1H(+)I(3)(-), 1H(+)I(5)(-), 2 . I-2, and 2H+I-3(-). Crystals suitable for X-ray structure determination have been obtained only for 1H+I-3(-). All the solids were characterized by FT-Raman and FT-IR spectroscopies in the region ofthe v(I-I) frequencies. Studies in solution have been carried out on each of the reactions between 1, 2, and N-methylmorpholine (3) with I-2. The formation constants of the 1:1 adducts of 2 and 3 determined at 20 degrees C by UV-visible spectroscopy are 8500 and 8400 dm(3) mol(-1), respectively. IR spectroscopy shows that I-2 binds the nitrogen of 1 and 2 both in axial and equatorial positions. Further FT-Raman and C-13 NMR spectroscopies support the nature of weak adducts berween 1 (2) and the molecular diiodine in solution. (C) 1997 John Wiley & Sons, Inc.
Related Products of 100-13-0, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 100-13-0 is helpful to your research.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem