Chemistry is an experimental science, Name: 2-Phenylethanol, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 60-12-8, Name is 2-Phenylethanol, molecular formula is C8H10O, belongs to thiomorpholine compound. In a document, author is Savkov, Boris Y..
Unusual Synthesis of Triosmium Carbene Clusters by Tandem Activation of Chlorohydrocarbons and Heterocyclic Amines
Reactions of the [Os3H2(CO)(10)] cluster complex (1) with six-membered heterocyclic amines (morpholine, thiomorpholine, piperidine) and halohydrocarbons (CH2Cl2, ClHC=CHCl, CH2=CCl2) at similar to 25 degrees C have been studied. Two main types of products are formed in all studied reactions. One product is carbene cluster [Os-3(mu-H)(mu-Cl){eta(1)-C(CH3)N(CH2CH2)(2)X}(CO)(9)] (X=O, S, CH2) (3, 3 a and 3 b). Second product is cluster containing enamine ligand [Os-3(mu-H){mu-CH=CHN(C2CH2)(2)X)}(2)(CO)(10)] (X=O, S, CH2) (2, 2 a and 2 b). The carbene ligand is assembled on a cluster, from three organic molecules, thus representing the first example of carbene ligands formed in this way. Clusters with carbene ligand exist as two stable isomers (rotamers hindered towards the Os-C bond), as confirmed by NMR studies and conformational analysis. We have found that in reactions of cluster 1 with acyclic amines containing an oxygen atom in gamma-position (likely morpholine in CH2Cl2), only complexes with bridging enamine ligands are formed. Compounds 2 a, 2 b, 3 and 3 b are characterized by single-crystal X-ray diffraction.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data. If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 60-12-8, in my other articles. Name: 2-Phenylethanol.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem