Chemistry is the experimental science by definition. We want to make observations to prove hypothesis. For this purpose, we perform experiments in the lab. , COA of Formula: C21H30N2, 13680-35-8, Name is 4,4-Methylenebis(2,6-diethylaniline), molecular formula is C21H30N2, belongs to thiomorpholine compound. In a document, author is Amezcua, CA, introduce the new discover.
Synthesis and comparative reactivity of thiomorpholine-borane: aqueous hydrolysis and oxidation by hypochlorite
Thiomorpholine-N-borane was synthesized via amine displacement of BH3 from tetrahydrofuran-borane which had been prepared from NaBH4 and BF3. Et2O in tetrahydrofuran. Acid-catalyzed hydrolysis occurs only slightly faster than for morpholine-borane, the difference being attributed to a small difference in the electronic inductive effects of sulfur and oxygen in the 4-position of the respective adducts. Reaction with NaOCl exhibits a stoichiometric [OCl-]:[S(CH2)(4)NHBH3] ratio of 5:1. This is attributed to consumption of 3 mol of hypochlorite for the oxidation of hydridic hydrogen in BH3, one for the chlorination of nitrogen and another in attack at sulfur presumably resulting in sulfoxide formation. At pH 9.1-10.4, the initial reaction of hypochlorite with thiomorpholine-borane is several times faster than with morpholine-borane and, unlike the reaction with morpholine-borane, relatively insensitive to pH. Whereas hypochlorite oxidation of morpholine-borane has been proposed to occur primarily through reaction with HOCl, it is speculated that thiomorpholine-borane is also susceptible to attack by hypochlorite ion. (C) 1999 Elsevier Science S.A. All rights reserved.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law. In my other articles, you can also check out more blogs about 13680-35-8. COA of Formula: C21H30N2.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem