In an article, author is Kralova, Petra, once mentioned the application of 827-95-2, Formula: C7H4NNaO4, Name is Sodium 3-nitrobenzoate, molecular formula is C7H4NNaO4, molecular weight is 189.1, MDL number is MFCD00051097, category is thiomorpholine. Now introduce a scientific discovery about this category.
Polymer-Supported Stereoselective Synthesis of Benzoxazino[4,3-b][1,2,5]thiadiazepinone 6,6-dioxides
Herein, we report the stereoselective synthesis of trisubstituted benzoxazino[4,3-b]{1,2,5}thiadiazepinone 6,6-dioxides from polymer-supported Fmoc-Ser(tBu)-OH and Fmoc-Thr(tBu)-OH. After the solid-phase synthesis of N-alkylated-Nsulfonylated intermediates using various 2-nitrobenzenesulfonyl chlorides and bromoketones, the target compounds were obtained via trifluoroacetic acid (TFA)-mediated cleavage from the resin, followed by cyclization of the diazepinone scaffold. Except for the threonine-based intermediates, the inclusion of triethylsilane (TES) in the cleavage cocktail yielded a specific configuration of the newly formed C-3 chiral center. The final cyclization resulted in minor or no inversion of the C-12a stereocenter configuration.
If you are interested in 827-95-2, you can contact me at any time and look forward to more communication. Formula: C7H4NNaO4.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem