Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics, 1633-22-3, Name is Tricyclo[8,2,2,24,7]hexadeca-4,6,10,12,13,15-hexaene, SMILES is C1(C=C2)=CC=C2CCC(C=C3)=CC=C3CC1, belongs to thiomorpholine compound. In a document, author is Moskalik, M. Yu., introduce the new discover, Computed Properties of C16H16.
Reaction of trifluoromethanesulfonamide with heterodienes under oxidation conditions
Reactions of trifluoromethanesulfonamide with divinyl sulfone, divinyl sulfoxide, divinyl sulfide, diphenyl sulfide, vinyl allyl and diallyl ethers was investigated in the presence of oxidation system t-BuOCl + NaI. The reaction with divinyl sulfone afforded a product of 1,5-heterocyclization, 2,6-diiodo-4-[(trifluoromethyl) sulfonyl]thiomorpholine 1,1-dioxide. The same product was obtained in the reaction with divinyl sulfoxide apparently due to its preliminary oxidation to sulfone. In reactions with divinyl sulfide and unsaturated ethers only the oxidation of substrates was observed accompanied with strong tarring; the products of a reaction with trifluoromethanesulfonamide were absent. With diphenyl sulfide a product was formed resulting from the oxidation at the sulfur atom [S(II) -> S(IV)], N-(diphenyl-lambda(4)-sulfanylidene)trifluoromethanesulfonamide.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 1633-22-3 is helpful to your research. Computed Properties of C16H16.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem