Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media, causing turnover rates to depend strongly on interfacial structure and composition, 489-84-9, Name is Guaiazulene, SMILES is CC1=C2C=CC(C)=C2C=C(C(C)C)C=C1, in an article , author is Szawkalo, Joanna, once mentioned of 489-84-9, SDS of cas: 489-84-9.
Synthesis and dynamic stereochemistry of 4-aryl-thiomorpholine-3,5-dione derivatives
A series of new N-aryl-substituted thiomorpholine-3,5-diones were synthesized. Crystal structures of seven compounds were established on the basis of X-ray crystallography. Stable at room temperature diastereomers were detected for (2-phenyl)-substituted derivatives using H-1 NMR. The dynamic stereochemistry of compound 36 was studied with variable-temperature H-1 NMR and the mechanism of diastereomers interconversion was proposed on the basis of quantum chemical calculations. (C) 2014 Elsevier B.V. All rights reserved.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem