Reference of 90-30-2, Irreversible inhibitors are therefore the equivalent of poisons in heterogeneous catalysis. 90-30-2, Name is N-Phenyl-1-naphthylamine, SMILES is N(C1=CC=CC=C1)C1=CC=CC2=C1C=CC=C2, belongs to thiomorpholine compound. In a article, author is Jarvis, Claire L., introduce new discover of the category.
Redox-Neutral alpha-Sulfenylation of Secondary Amines: Ring-Fused N,S-Acetals
Secondary amines react with thiosalicylaldehydes in the presence of catalytic amounts of acetic acid to generate ring-fused N,S-acetals in redox-neutral fashion. A broad range of amines undergo alpha-sulfenylation, including challenging substrates such morpholine, thiomorpholine, and piperazines. Computational studies employing density functional theory indicate that acetic acid reduces the energy barriers of two separate steps, both of which involve proton transfer.
Reference of 90-30-2, The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, spectroscopic. I hope my blog about 90-30-2 is helpful to your research.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem