As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. In an article, author is Li, YX, once mentioned the application of 114-83-0, Name is 1-Acetyl-2-phenylhydrazine, molecular formula is C8H10N2O, molecular weight is 150.1778, MDL number is MFCD00008672, category is thiomorpholine. Now introduce a scientific discovery about this category, Formula: C8H10N2O.
Transition metal complexes of 1,3-bis(thiomorpholino)propane: crystal structure and dynamic H-1 NMR study
Complexes of 1,3-bis(thiomorpholino)propane (L) with Zn(II), Pd(II), Pt(II) and Rh(III) of the formula [ZnLCl2], [ML](ClO4)(2), (M = Pd and Pt), [RhLCl2]Cl . 4H(2)O and [RhLCl2]PF6 were prepared and characterised. The molecular structures of [ZnLCl2], [PdL](ClO4)(2) and [RhLCl2]PF6 were determined by X-ray diffraction. In [ZnLCl2], the ligand acts in a bidentate fashion using its two N atoms while the two S atoms remain free and the coordination structure is a distorted tetrahedron. [PdL](ClO4)(2) possesses a distorted square planar coordination geometry with all the four hetero atoms being coordinated. The coordination structure of [RhLCl2]PF6 is a distorted octahedron with the two Cl atoms in trans position and L also acting as a tetradentate ligand. In addition to the crystal structures, the dynamic H-1 NMR behaviour of the three complexes were also investigated. (C) 1999 Elsevier Science S.A. All rights reserved.
Formula: C8H10N2O, The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, spectroscopic. I hope my blog about 114-83-0 is helpful to your research.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem