The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. In an article, author is Deniz, Nahide Gulsah, once mentioned the application of 13120-77-9, Name is 2-Methyl-5-nitroanisole, molecular formula is C8H9NO3, molecular weight is 167.16, MDL number is MFCD00043912, category is thiomorpholine. Now introduce a scientific discovery about this category, Category: thiomorpholine.
The Vinylic S-N Reactions of Nitrodienes with Heteroatom-Substituted Nuchleophilies and Their Structural Studies
Herein, we report the reactions of 1,1,2,4,4-pentachloro-3-nitro-1,3-butadiene 1a and (1Z)-1-bromo-1,2,4,4-tetrachloro-3-nitro-1,3-butadiene 1b with nitrogen- and sulfur-containing nucleophiles to obtain highly functionalized S-, S,S-, S,S,S-, S,O- and N,S-substituted-polyhalodiene-3-nitro-1,3-butadiene derivatives. Most of these reactions turned out to be highly selective with good to very good yields. All new compounds have been characterized by nuclear magnetic resonance spectroscopy, mass spectrometry, and Fourier transform infrared spectroscopy spectroscopic data. The molecular structures of the 3a and 21a due to its exceptional substitution pattern were evidenced by the X-ray single-crystal diffraction method.
Category: thiomorpholine, The potential utility of systematic synthetic strategy will be applicable to efficient generations of chemical libraries of compounds to find hit molecules. I hope my blog about 13120-77-9 is helpful to your research.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem