Catalysts allow a reaction to proceed via a pathway that has a lower activation energy than the uncatalyzed reaction. , HPLC of Formula: C10H12O3, 104-21-2, Name is 4-Methoxybenzyl acetate, molecular formula is C10H12O3, belongs to thiomorpholine compound. In a document, author is Hanif, KM, introduce the new discover.
Ring-opening reactions of thiomorpholine and thiazolidine by [Ru-3(CO)(12)]: crystal structures of [Ru-3(mu-H)(mu-eta(2)-SCH2CH2NH2)(CO)(9)] and [Ru-2(mu-eta(3)-SCH2CH2NHCH2)(CO)(6)]
The reaction of thiomorpholine (C4H9NS) with [Ru-3(CO)(12)] at 68 degrees C afforded [Ru-3(mu-H)(mu-eta(2)-SCH2CH2NH2)(CO)(9)] 5 in 25% yield. An X-ray structure determination of 5 showed that it consists of a closed triruthenium cluster with a mu-eta(2)-SCH2CH2NH2 ligand formed by the ring-opening cleavage of thiomorpholine with elimination of a C-2 fragment. In contrast the analogous reaction of thiazolidine (C3H7NS) with [Ru-3(CO)(12)] yielded the dinuclear compound [Ru-2(mu-eta(3)-SCH2CH2NHCH3)(CO)(6)] 6 (28%), which was found to contain a mu-eta(3)-SCH2CH2NHCH2 ligand formed by the ring-opening cleavage of the C-S bond of the thiazolide ligand. (C) 1999 Elsevier Science S.A. All rights reserved.
Future efforts will undeniably focus on the diversification of the new catalytic transformations. These may comprise an expansion of the substrate scope from aromatic and heteroaromatic compounds to other hydrocarbons. 104-21-2, you can contact me at any time and look forward to more communication. HPLC of Formula: C10H12O3.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem