In heterogeneous catalysis, catalysts provide a surface to which reactants bind in a process of adsorption. In homogeneous catalysis, catalysts are in the same phase as the reactants. 21436-98-6, Name is 2,6-Dimethylaniline hydrochloride, molecular formurla is C8H12ClN. In a document, author is Jeon, Youngeun, introducing its new discovery. COA of Formula: C8H12ClN.
Controlled Reversible Crystal Transformation of Cu(I) Supramolecular Isomers
Four copper(I) coordination polymers (CPs), {[CuIL]center dot CH3CN]}(n) (1), {[CuIL]center dot CHCl3}(n) (2), {[CuIL]center dot CH2Cl2}(n) (3), and [CuIL](n) (4), were prepared by self-assembly reactions between CuI and (2-pyrazinylcarbonyl)thiomorpholine (L). CPs 1-4 are interconnected by rhomboid Cu-I-2-Cu units. CPs 1 and 4 have one-dimensional loop-chain structures, and 2 and 3 adopt two-dimensional network structures. CPs 1-4 are pseudopolymorphic supramolecular isomers. CPs 2′ and 3′ are prepared by removal of solvate molecules from CPs 2 and 3, which are polymorphic supramolecular isomers with CP 4. Reversible crystal-to-crystal transformations were observed under appropriate conditions such as solvent or heat.
Therefore, this conceptually novel strategy might open impressive avenues to establish green and sustainable chemistry platforms.If you are interested in 21436-98-6, you can contact me at any time and look forward to more communication. COA of Formula: C8H12ClN.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem