In heterogeneous catalysis, catalysts provide a surface to which reactants bind in a process of adsorption. In homogeneous catalysis, catalysts are in the same phase as the reactants. 90-15-3, Name is 1-Naphthol, molecular formurla is C10H8O. In a document, author is Schwan, Adrian L., introducing its new discovery. Product Details of 90-15-3.
Origins and applications of stereoselective sulfenate anion alkylation reactions
Selected sulfenate anions can be alkylated with diastereoselectivities near 9:1 when there is appropriately positioned carbon chirality in the sulfenate structure or in the alkylation electrophile. Both protocols represent a conceptually different approach to beta-amino sulfoxides. When vinylic beta-amino sulfoxides are cyclized, thiomorpholine S-oxides result, and substrate control over the stereochemistry of alkyl substituents was found. This finding facilitates the synthesis of cis and trans dialkylpyrrolidines, known ant venom alkaloids. A computational model is demonstrated to account for some of the diastereoselection results. The importance of intramolecular interactions of sulfenate constituent atoms with pendent substituents is established.
Product Details of 90-15-3, The reactant in an enzyme-catalyzed reaction is called a substrate. Enzyme inhibitors cause a decrease in the reaction rate of an enzyme-catalyzed reaction.I hope my blog about 90-15-3 is helpful to your research.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem