The main research directions are chemical synthesis, new energy materials, nano-ceramics, nano-hybrid composite materials, preparation and modification of special coatings, and research on the structure and performance of functional materials. 492-37-5, Name is 2-Phenylpropionic acid, molecular formurla is C9H10O2. In a document, author is Bell, NA, introducing its new discovery. Category: thiomorpholine.
Distorted electron acceptors: an unexpected reaction involving tetramethyl-TCNQ
Reactions involving the donors N-methyl-2-methylbenzothiazolium-andN-(1-propyl)-2-methylbenzothiazolium iodide with the acceptor 2,3,5,6-tetramethyl-7,7,8,8-tetracyano-p-quinodimethane (TMTCNQ) in the presence of a suitable base lead to the isolation of novel [(Z)-beta-(N-alkylbenzothiazol-3-ium-2-yl)-alpha-cyano-2,3,5,6-tetramethyl-4-styryl]dicyanomethanide chromophores. Under prolonged reaction periods, these first examples of charge transfer compounds incorporating the distorted TMTCNQ electron acceptor, undergo further reaction at the acrylonitrile functionality promoting the synthesis of novel thiomorpholine-based charge transfer compounds via a sulfur mediated cyclisation reaction. This second reaction illustrates a fundamentally new type of TCNQ-based chemistry as confirmed by X-ray crystallography and high-resolution mass spectrometry. A possible reaction mechanism for the formation of the thiomorpholine-based chromophores is considered.
The catalyzed pathway has a lower Ea, but the net change in energy that results from the reaction is not affected by the presence of a catalyst. Interested yet? Read on for other articles about 492-37-5, you can contact me at any time and look forward to more communication. Category: thiomorpholine.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem