The main research directions are chemical synthesis, new energy materials, nano-ceramics, nano-hybrid composite materials, preparation and modification of special coatings, and research on the structure and performance of functional materials. 607-81-8, Name is Diethyl benzylmalonate, molecular formurla is C14H18O4. In a document, author is Beller, M, introducing its new discovery. Application In Synthesis of Diethyl benzylmalonate.
The oxidative anti-Markovnikov amination of styrenes catalyzed by cationic rhodium complexes provides a new access to enamines. As catalyst precursors [Rh(cod)(amine)(2)](+) complexes have been identified and characterized for the first time by X-ray crystallography and NMR. While piperazine, N-methylpiperazine, and thiomorpholine form 1:1 Rh-amine complexes, nonchelating amines such as piperidine and diethylamine form 1:2 Rh-amine complexes. The easier dissociation of the amine ligand explains why monodentate amines give good yields of the corresponding enamines in contrast to bidentate amines. (C) 1998 Elsevier Science S.A. All rights reserved.
The catalyzed pathway has a lower Ea, but the net change in energy that results from the reaction is not affected by the presence of a catalyst. Interested yet? Read on for other articles about 607-81-8, you can contact me at any time and look forward to more communication. Application In Synthesis of Diethyl benzylmalonate.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem