The main research directions are chemical synthesis, new energy materials, nano-ceramics, nano-hybrid composite materials, preparation and modification of special coatings, and research on the structure and performance of functional materials. 103-67-3, Name is N-Methyl-1-phenylmethanamine, molecular formurla is C8H11N. In a document, author is Dal Magro, J, introducing its new discovery. HPLC of Formula: https://www.ambeed.com/products/103-67-3.html.
The kinetics of the nitrosation of 2-hydroxyethylpiperidine have been studied in acidic (0.05-0.30 mol dm(-3) HClO4) aqueous media. The reaction rate is first order with respect to nitrite and amine and independent of acidity and shows an experimental isotope effect of 1.73. The most plausible mechanism involves the fast formation of an alkyl nitrite in the protonated amine (equilibrium constant estimated as 0.014 dm(3) mol(-1)). The loss of a proton from this intermediate is the rate-limiting step, and it is followed by a fast internal nitroso group transfer from the oxygen to the nitrogen atom to give the corresponding N-nitroso compound. A comparison of this nitrosation pathway of secondary amines in acid media with the nitrosation of thiomorpholine and piperidine, and with that of amines by alkyl nitrites in basic media is also discussed.
Future efforts will undeniably focus on the diversification of the new catalytic transformations. These may comprise an expansion of the substrate scope from aromatic and heteroaromatic compounds to other hydrocarbons. 103-67-3, you can contact me at any time and look forward to more communication. HPLC of Formula: https://www.ambeed.com/products/103-67-3.html.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem