In heterogeneous catalysis, catalysts provide a surface to which reactants bind in a process of adsorption. In homogeneous catalysis, catalysts are in the same phase as the reactants. 3068-76-6, Name is N-(3-(Trimethoxysilyl)propyl)aniline, molecular formurla is C12H21NO3Si. In a document, author is Sovilj, SP, introducing its new discovery. Recommanded Product: 3068-76-6.
Five new Cu-II complexes of general formula [Cu-2(Rdtc)tpmc](ClO4)(3), (1)-(5), where tpmc and Rdtc(-) refer to N,N’,N,N’-tetrakis(2-pyridylmethyl)-1,4,8,11-teraazacyclotetradecane and piperidine- (Pipdtc), 4-morpholine-(Morphdtc), 4-thiomorpholine- (Timdtc), piperazine- (Pzdtc) or N-methylpiperazine- (N-Mepzdtc) dithiocarbamates, respectively, have been prepared. Elemental analyses, conductometric and magnetic measurements, u.v./vis, i.r., e.p.r. and mass spectroscopy have been employed to characterize them. The complexes adopt an exo coordination of CuII ions and tpmc. The dithiocarbamate ion joins both the sulphur and the copper atoms acting as a bridging ligand The presence of different heteroatoms in the piperidine ring influences the nu(Cdouble bondN) and nu(Cdouble bondS) vibrations which decrease in the order of the complexes: Pipdtc > N-Mepipdtc > Pzdtc > Morphdtc > Timdtc ligands. Attention has been paid to the detailed mechanism of the mass spectral fragmentation of the complexes. The g(eff) factors of the complexes have been also estimated by e.p.r. spectra. Finally, the complexes obtained demonstrate microbiologycal activity against some bacteria.
Future efforts will undeniably focus on the diversification of the new catalytic transformations. These may comprise an expansion of the substrate scope from aromatic and heteroaromatic compounds to other hydrocarbons. 3068-76-6, you can contact me at any time and look forward to more communication. Recommanded Product: 3068-76-6.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem