As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. In an article, author is Efimenko, I. A., once mentioned the application of 114-83-0, Name is 1-Acetyl-2-phenylhydrazine, molecular formula is C8H10N2O, molecular weight is 150.1778, MDL number is MFCD00008672, category is thiomorpholine. Now introduce a scientific discovery about this category, Recommanded Product: 1-Acetyl-2-phenylhydrazine.
Binary alpha-unsaturated palladium carboxylates have been synthesized by substitution of alpha-unsaturated acids RCOOH (R is CH2=C(Me), MeCH=CH, PhCH=CH) for the acetate ion in Pd-3(mu-MeCOO)(6). These carboxylates react with amines A (A is morpholine (M), methylmorpholine (MM), or thiomorpholine (MS)) to give trans-Pd(A)(2)(RCOO)(2) similar to trans-A(2)(MeCO2)(2). The structures of the trans-Pd(A)(2)(RCOO)(2) complexes (R is MeCH=CH; A is M, MM, MS) have been determined by X-ray crystallography. The effect of solvent on the crystal structure of the complexes has been demonstrated for trans-(MeCH=CHCO2)(2)Pd(C4H9NO)(2) as an example. The amination reaction of palladium carbonyl crotonate with a secondary amine, morpholine, has been studied for the first time. The reaction involves disproportionation of Pd(I) into Pd(0) and Pd(II) and leads to the first unsaturated palladium(II) carbamoyl carboxylate-palladium carbamoyl crotonate trans-(OC4H8NH)(2)Pd[OC4H8NC(=O)](MeCH=CHCO2) center dot H2O, as well as to trans-M2Pd(MeCH=CHCO2)(2) and (C4H10NO)(+)(MeCH=CHCO2)(-). The structures of these compounds have been proved by X-ray crystallography.
Recommanded Product: 1-Acetyl-2-phenylhydrazine, The prevalence of solvent effects in heterogeneous catalysis in condensed media has motivated developing quantitative kinetic, spectroscopic. I hope my blog about 114-83-0 is helpful to your research.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem