New Advances in Chemical Research, May 2021. The prevalence of solvent effects has motivated developing quantitative kinetic, and theoretical assessments of solvent structures and their interactions with reaction intermediates. In an article, author is Efimenko, I. A., once mentioned the application of 599-61-1, Name is 3,3′-Sulfonyldianiline, molecular formula is C12H12N2O2S, molecular weight is 248.3, MDL number is MFCD00007792, category is thiomorpholine. Now introduce a scientific discovery about this category, Reference of 599-61-1.
Binary alpha-unsaturated palladium carboxylates have been synthesized by substitution of alpha-unsaturated acids RCOOH (R is CH2=C(Me), MeCH=CH, PhCH=CH) for the acetate ion in Pd-3(mu-MeCOO)(6). These carboxylates react with amines A (A is morpholine (M), methylmorpholine (MM), or thiomorpholine (MS)) to give trans-Pd(A)(2)(RCOO)(2) similar to trans-A(2)(MeCO2)(2). The structures of the trans-Pd(A)(2)(RCOO)(2) complexes (R is MeCH=CH; A is M, MM, MS) have been determined by X-ray crystallography. The effect of solvent on the crystal structure of the complexes has been demonstrated for trans-(MeCH=CHCO2)(2)Pd(C4H9NO)(2) as an example. The amination reaction of palladium carbonyl crotonate with a secondary amine, morpholine, has been studied for the first time. The reaction involves disproportionation of Pd(I) into Pd(0) and Pd(II) and leads to the first unsaturated palladium(II) carbamoyl carboxylate-palladium carbamoyl crotonate trans-(OC4H8NH)(2)Pd[OC4H8NC(=O)](MeCH=CHCO2) center dot H2O, as well as to trans-M2Pd(MeCH=CHCO2)(2) and (C4H10NO)(+)(MeCH=CHCO2)(-). The structures of these compounds have been proved by X-ray crystallography.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem