New Advances in Chemical Research in 2021. Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. In an article, author is Ilgin, Pinar, once mentioned the application of 179526-95-5, Name is 2-Bromo-4′-chloro-1,1′-biphenyl, molecular formula is C12H8BrCl, molecular weight is 267.55, MDL number is MFCD18072809, category is thiomorpholine. Now introduce a scientific discovery about this category, Application In Synthesis of 2-Bromo-4′-chloro-1,1′-biphenyl.
In this study, firstly N-metacrylamido thiomorpholine containing thioether group was synthesized as monomer. Then, p(AAm-co-MTM) hydrogels were prepared from the redox polymerization of acrylamide and N-metacrylamido thiomorpholine as a selective support material. p(AAm-co-MTM) hydrogel-gold nanoparticles were obtained as a result of the reduction of the selectively absorbed gold(III) ions by the hydrogel network using NaBH 4 as reducing agent. All materials were characterized using techniques such as SEM, EDX, TEM and XRD analysis. It was determined that p(AAm-co-MTM)-Au composite material has high catalytic activity for the reduction of 4-nitrophenol. The activation parameters of the reduction reaction of 4-nitrophenol using NaBH4 in the presence of p(AAm-co-MTM)-Au catalyst were calculated as E-a = 38.80 kJ/mol, Delta H-# = 36.16 kJ/mol and Delta S-# = – 161.37 J/mol K.
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis.you can check my other blog about 179526-95-5, you can contact me at any time and look forward to more communication. Application In Synthesis of 2-Bromo-4′-chloro-1,1′-biphenyl.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem