Chemical Research Letters, May 2021. Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media. 30379-55-6, Name is 2-(Benzyloxy)acetic acid, molecular formurla is C9H10O3. In a document, author is Ibis, Cemil, introducing its new discovery. Computed Properties of https://www.ambeed.com/products/30379-55-6.html.
Thiosubstituted nitrodien compounds 1a-f are obtained from 2-nitropentachlorobutadiene and some alifatic thiols. Compounds 1a-f have reacted with thiomorpholine 2 and yielded 3a-f in CH2Cl2. The compounds 5a-f have been obtained by the reactions of 1a-f with N-(diphenylmethyl)piperazine 4 in CH2Cl2. 2-Nitro-3,4,4-trichloro-1-(ethylthio)-1-[4-(1-diphenylmethyl)-piperazin-1-yl]-1,3-butadiene 5a is synthesized and its crystal structure is determined. The compound 5a crystallizes in the orthorhombic crystal system (space group P2(1)2(1)2(1)) with the unit cell parameters a = 9.4240(2) angstrom, b = 14.4007(2) angstrom, c = 18.1891(2) angstrom, alpha, beta, gamma = 90 degrees, V = 2468.48(7) angstrom(3), Z = 4. The structure has been solved by direct methods (SIR92) and refined to the residual index R-1 = 0.078.
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis.you can check my other blog about 30379-55-6, you can contact me at any time and look forward to more communication. Computed Properties of https://www.ambeed.com/products/30379-55-6.html.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem