Computed Properties of https://www.ambeed.com/products/53499-40-4.html, New discoveries in chemical research and development in 2021.The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 53499-40-4, Name is 2-(Benzhydryloxy)-N-methylethanamine hydrochloride, SMILES is CNCCOC(C1=CC=CC=C1)C2=CC=CC=C2.[H]Cl, molecular formula is C16H20ClNO, belongs to thiomorpholine compound. In an article, author is Ilgin, Pinar, introduce new discover of the category.
In this study, firstly N-metacrylamido thiomorpholine containing thioether group was synthesized as monomer. Then, p(AAm-co-MTM) hydrogels were prepared from the redox polymerization of acrylamide and N-metacrylamido thiomorpholine as a selective support material. p(AAm-co-MTM) hydrogel-gold nanoparticles were obtained as a result of the reduction of the selectively absorbed gold(III) ions by the hydrogel network using NaBH 4 as reducing agent. All materials were characterized using techniques such as SEM, EDX, TEM and XRD analysis. It was determined that p(AAm-co-MTM)-Au composite material has high catalytic activity for the reduction of 4-nitrophenol. The activation parameters of the reduction reaction of 4-nitrophenol using NaBH4 in the presence of p(AAm-co-MTM)-Au catalyst were calculated as E-a = 38.80 kJ/mol, Delta H-# = 36.16 kJ/mol and Delta S-# = – 161.37 J/mol K.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem