New Advances in Chemical Research in 2021. Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. In an article, author is Wei, Wen-Juan, once mentioned the application of 84-65-1, Name is Anthracene-9,10-dione, molecular formula is C14H8O2, molecular weight is 208.21, MDL number is MFCD00001188, category is thiomorpholine. Now introduce a scientific discovery about this category, Quality Control of Anthracene-9,10-dione.
We have successfully synthesized a new antimony-based halide hydrate, bis(thiomorpholine) pentachloroantimonate(III) monohydrate (C4NSH10)(2)[SbCl5]center dot H2O (1, C4NSH10+ is thiomorpholine cation), which crystals in a centrosymmetric space group of Pbca. 1 features the R2MX5-type perovskite architecture and undergoes a first-order structural phase transition (PT) at 406.3 K, accompanying with prominent dielectric responses. The photoluminescence spectra reveal that 1 shows a broadband light emission and a long lifetime (2.77 mu s). In addition, the DFT calculation exhibits the organic thiomorpholine cation has a contribution to electronic band structures of 1, which is distinct with other halide bismuth (Bi) and antimony (Sb)-based hybrid perovskites. This finding opens up a potential pathway to construct new lead-free hybrid materials for application of the optoelectronics. (C) 2020 Elsevier B.V. All rights reserved.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem