New research progress on 177034-57-0 in 2021. In classical electrochemical theory, both the electron transfer rate and the adsorption of reactants at the electrode control the electrochemical reaction. 177034-57-0, Name is 4-((2-Isopropoxyethoxy)methyl)phenol, molecular formurla is C12H18O3. In a document, author is Banerjee, Subhadeep, introducing its new discovery. Related Products of 177034-57-0.
trans-Diolchlorin was prepared by nucleophilic addition of methyl-Grignard bromide to meso-tetraphenyl-2,3-dioxoporphyrin, as its free base or Ni(II) complex. The trans-configuration of the vic-diol functionality was shown by single crystal X-ray diffractometry. The nickel complex of the trans-dimethyldiol proved susceptible to Pb(IV) acetate-induced, oxidative diol cleavage, generating a meso-tetraphenylsecochlorin bismethylketone Ni(II) complex, the first example of this chromophore class. Under Bronsted-basic conditions, this bisketone cyclized via an intramolecular aldol condensation to provide a meso-tetraphenyloxypyriporphyrin. Reduction of this porphyrin analog saturated the double bond in the pyridinone moiety, generating an oxypyrichlorin. Reaction of the meso-tetraphenylsecochlorin bismethylketone Ni(II) complex with Lawesson’s reagent induced the formation of a thiomorpholinochlorin substituted with two methylene groups, the first example of any porphyrin analog containing a thiomorpholine moiety.
I am very proud of our efforts over the past few months and hope to 177034-57-0 help many people in the next few years. Related Products of 177034-57-0.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem