New Advances in Chemical Research in 2021. Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. In an article, author is Szawkalo, Joanna, once mentioned the application of 115-86-6, Name is Triphenyl phosphate, molecular formula is C18H15O4P, molecular weight is 326.2831, MDL number is MFCD00003031, category is thiomorpholine. Now introduce a scientific discovery about this category, Electric Literature of 115-86-6.
A series of new N-aryl-substituted thiomorpholine-3,5-diones were synthesized. Crystal structures of seven compounds were established on the basis of X-ray crystallography. Stable at room temperature diastereomers were detected for (2-phenyl)-substituted derivatives using H-1 NMR. The dynamic stereochemistry of compound 36 was studied with variable-temperature H-1 NMR and the mechanism of diastereomers interconversion was proposed on the basis of quantum chemical calculations. (C) 2014 Elsevier B.V. All rights reserved.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem