Synthetic Route of 147-93-3, New discoveries in chemical research and development in 2021.The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 147-93-3, Name is 2-Mercaptobenzoic acid, SMILES is O=C(O)C1=CC=CC=C1S, molecular formula is C7H6O2S, belongs to thiomorpholine compound. In an article, author is Xie, Lei, introduce new discover of the category.
Base-mediated [3 + 3] cycloaddition reaction of in-situ formed aza-oxyallyl cations and 1,4-dithiane-2,5-diols has been achieved under mild reaction conditions. This strategy provides direct and efficient access to prepare desired thiomorpholin-3-one derivatives in moderate-to-high yields. The approach features broad substrates scope and short reaction time. Moreover, the resulting products can be readily converted into other useful heterocyclic compounds including 2H-1,4-thiazin-3(4H)-ones and thiomorpholine-3,5-diones.
Synthetic Route of 147-93-3, You can get involved in discussing the latest developments in this exciting area about 147-93-3.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem