New discoveries in chemical research and development in 2021. The dynamic chemical diversity of the numerous elements, ions and molecules that constitute the basis of life provides wide challenges and opportunities for research. In an article, author is Sovilj, SP, once mentioned the application of 3068-76-6, Name is N-(3-(Trimethoxysilyl)propyl)aniline, molecular formula is C12H21NO3Si, molecular weight is 255.3855, MDL number is MFCD00053673, category is thiomorpholine. Now introduce a scientific discovery about this category, Safety of N-(3-(Trimethoxysilyl)propyl)aniline.
Five new Cu-II complexes of general formula [Cu-2(Rdtc)tpmc](ClO4)(3), (1)-(5), where tpmc and Rdtc(-) refer to N,N’,N,N’-tetrakis(2-pyridylmethyl)-1,4,8,11-teraazacyclotetradecane and piperidine- (Pipdtc), 4-morpholine-(Morphdtc), 4-thiomorpholine- (Timdtc), piperazine- (Pzdtc) or N-methylpiperazine- (N-Mepzdtc) dithiocarbamates, respectively, have been prepared. Elemental analyses, conductometric and magnetic measurements, u.v./vis, i.r., e.p.r. and mass spectroscopy have been employed to characterize them. The complexes adopt an exo coordination of CuII ions and tpmc. The dithiocarbamate ion joins both the sulphur and the copper atoms acting as a bridging ligand The presence of different heteroatoms in the piperidine ring influences the nu(Cdouble bondN) and nu(Cdouble bondS) vibrations which decrease in the order of the complexes: Pipdtc > N-Mepipdtc > Pzdtc > Morphdtc > Timdtc ligands. Attention has been paid to the detailed mechanism of the mass spectral fragmentation of the complexes. The g(eff) factors of the complexes have been also estimated by e.p.r. spectra. Finally, the complexes obtained demonstrate microbiologycal activity against some bacteria.
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis.you can check my other blog about 3068-76-6, you can contact me at any time and look forward to more communication. Safety of N-(3-(Trimethoxysilyl)propyl)aniline.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem