New Advances in Chemical Research in 2021. Redox catalysis has been broadly utilized in electrochemical synthesis due to its kinetic advantages over direct electrolysis. In an article, author is Xie, Lei, once mentioned the application of 1031-93-2, Name is Diphenyl(p-tolyl)phosphine, molecular formula is C19H17P, molecular weight is 276.3121, MDL number is MFCD00008543, category is thiomorpholine. Now introduce a scientific discovery about this category, Safety of Diphenyl(p-tolyl)phosphine.
Base-mediated [3 + 3] cycloaddition reaction of in-situ formed aza-oxyallyl cations and 1,4-dithiane-2,5-diols has been achieved under mild reaction conditions. This strategy provides direct and efficient access to prepare desired thiomorpholin-3-one derivatives in moderate-to-high yields. The approach features broad substrates scope and short reaction time. Moreover, the resulting products can be readily converted into other useful heterocyclic compounds including 2H-1,4-thiazin-3(4H)-ones and thiomorpholine-3,5-diones.
The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis.you can check my other blog about 1031-93-2, you can contact me at any time and look forward to more communication. Safety of Diphenyl(p-tolyl)phosphine.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem