Synthetic Route of 114-83-0, New discoveries in chemical research and development in 2021.The transformation of simple hydrocarbons into more complex and valuable products via catalytic C–H bond functionalisation has revolutionised modern synthetic chemistry. 114-83-0, Name is 1-Acetyl-2-phenylhydrazine, SMILES is CC(NNC1=CC=CC=C1)=O, molecular formula is C8H10N2O, belongs to thiomorpholine compound. In an article, author is Babic-Samardzija, K, introduce new discover of the category.
The inhibiting properties of four macrocyclic cobalt(III) complexes of the general formula [Co-III(Rdtc)cyclam](ClO2)(2), where cyclam and Rdtc(-) refer to 1.4.8,11-tetraazacyclotetradecane and morpholine-, thiomorpholine-, piperazine, N-methyipiperazine-dithiocarbamates. respectively. has been studied on the corrosion of iron in aerated 0.1 M HClO2 solutions by potentiodynamic polarization (dc) technique and electrochemical impedance spectroscopy (ac), Inhibitor efficiency for the corrosion of iron is found to be better for cobalt complexes then for related amino-ligands. The impedance increases with inhibitor concentration. Polarization curves indicate that the inhibitors are predominantly mixed-type. Better protection by the complex inhibitors was obtained with longer immersion time. The best fit for inhibitors adsorption is obtained using the Langmuir isotherm model. Molecular modeling calculations were used to correlate structural properties of the complex species and their inhibition efficiency. (C) 2004 Elsevier B.V. All rights reserved.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem