Chemical Research Letters, May 2021. Reactions catalyzed within inorganic and organic materials and at electrochemical interfaces commonly occur at high coverage and in condensed media. 2471-70-7, Name is 6-Methoxy-2-naphthoic acid, molecular formurla is C12H10O3. In a document, author is Morkved, Eva H., introducing its new discovery. Application of 2471-70-7.
The Zn(quinoline)(2)Cl-2 complex is found to be a convenient reagent for the direct synthesis of amino-substituted, zinc azaphthalocyanines. Octa(4-thiomorpholinyl)- and octa(1-pyrazolyl)- substituted zinc azaphthalocyanines were synthesized from pyrazines, 5,6-bis(4-thiomorpholinyl)pyrazine-2,3-dicarbonitrile and 5,6-bis(1-pyrazolyl)pyrazine-2,3-dicarbonitrile, respectively and dry Zn(quinoline)(2)Cl-2. Two zinc azaphthalocyanines, both mixtures of four constitutional isomers, were synthesized by the same method, from 6-(2-thienyl)-5-(4-thiomorpholinyl)pyrazine-2,3-dicarbonitrile and from 6-(2-thienyl)-5-(1-pyrazolyl)pyrazine-2,3-dicarbonitrile respectively. The octa(4-thiomorpholinyl)- and octa(1-pyrazolyl)-substituted zinc azaphthalocyanines and the zinc azaphthalocyanines with mixed substituents were characterized by elemental analyses, TOF-SIMS, H-1 and C-13 NMR, and UV-vis spectroscopic methods. Q-bands for octa(4-thiomorpholinyl)- and octa(I-pyrazolyl)-substituted zinc azaphthalocyanines and the zinc azaphthalocyanines with mixed substituents are found at respectively 655 and 670 nm (epsilon: 100 000-180 000 M-1.cm(-1)). Copyright (c) 2006 Society of Porphyrins & Phthalocyanines.
By the way, if you are interested in learning more fun chemistry with your kids, get your hands into one chemistry set now, and start enjoying the best part of chemistry: experiments about 2471-70-7. Application of 2471-70-7.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem