Electric Literature of 1965-09-9, New discoveries in chemical research and development in 2021.Chemistry can be defined as the study of matter and the changes it undergoes. 1965-09-9, Name is 4,4-Oxydiphenol, SMILES is OC1=CC=C(OC2=CC=C(O)C=C2)C=C1, belongs to thiomorpholine compound. In a article, author is Beller, M, introduce new discover of the category.
The oxidative anti-Markovnikov amination of styrenes catalyzed by cationic rhodium complexes provides a new access to enamines. As catalyst precursors [Rh(cod)(amine)(2)](+) complexes have been identified and characterized for the first time by X-ray crystallography and NMR. While piperazine, N-methylpiperazine, and thiomorpholine form 1:1 Rh-amine complexes, nonchelating amines such as piperidine and diethylamine form 1:2 Rh-amine complexes. The easier dissociation of the amine ligand explains why monodentate amines give good yields of the corresponding enamines in contrast to bidentate amines. (C) 1998 Elsevier Science S.A. All rights reserved.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem