Application In Synthesis of 4-Mercaptobenzoic acid, Chemical engineers ensure the efficiency and safety of chemical processes, adapt the chemical make-up of products to meet environmental or economic needs, and apply new technologies to improve existing processes. 1074-36-8, Name is 4-Mercaptobenzoic acid, SMILES is O=C(O)C1=CC=C(S)C=C1, belongs to thiomorpholine compound. In a article, author is Sovilj, SP, introduce new discover of the category.
Four new cobalt(III) complexes of the general formula [Co(Rdtc)cyclam](ClO4)(2), where cyclam and Rdtc(-) refer to 1,4,8,11-tetraazacyclotetradecane and 2-, 3-, 4-methylpiperidine (2-, 3-, 4-wMeepipdtc(-)) or 4-thiomorpholine (Timdtc(-)) dithiocarbamates, respectively, have been prepared. Elemental and thermal analyses, VIS, IR and H-1 and C-13 NMR spectroscopy have been used to characterized them. In the complexes, cobalt is hexa-coordinated in an octahedral geometry of a folded macrocyclic ligand and dithiocarbamates are bound as bidentates. As regards to the influence of the position of the methyl group on the piperidine ring, the nu(C – N) and nu(C – S) values increase in the order 2-Mepipdtc(-) < 3-Mepipdtc(-) < 4-Mepipdtc(-). Furthermore, the position of the methyl substituent also influences the thermal stability of the complexes and the order of stability decreases in the opposite order. Keep reading other articles of 1074-36-8. Don’t worry, you don’t need a PhD in chemistry to understand the explanations! Recommanded Product: 1074-36-8.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem