Researchers are common within chemical engineering and are often tasked with creating and developing new chemical techniques, frequently combining other advanced and emerging scientific areas. In an article, author is Sovilj, SP, once mentioned the application of 5428-54-6, Name is 2-Methyl-5-nitrophenol, molecular formula is C7H7NO3, molecular weight is 153.14, MDL number is MFCD00043909, category is thiomorpholine. Now introduce a scientific discovery about this category, Synthetic Route of 5428-54-6.
Four new cobalt(III) complexes of the general formula [Co(Rdtc)cyclam](ClO4)(2), where cyclam and Rdtc(-) refer to 1,4,8,11-tetraazacyclotetradecane and 2-, 3-, 4-methylpiperidine (2-, 3-, 4-wMeepipdtc(-)) or 4-thiomorpholine (Timdtc(-)) dithiocarbamates, respectively, have been prepared. Elemental and thermal analyses, VIS, IR and H-1 and C-13 NMR spectroscopy have been used to characterized them. In the complexes, cobalt is hexa-coordinated in an octahedral geometry of a folded macrocyclic ligand and dithiocarbamates are bound as bidentates. As regards to the influence of the position of the methyl group on the piperidine ring, the nu(C – N) and nu(C – S) values increase in the order 2-Mepipdtc(-) < 3-Mepipdtc(-) < 4-Mepipdtc(-). Furthermore, the position of the methyl substituent also influences the thermal stability of the complexes and the order of stability decreases in the opposite order. The result showed that such a combination of chemo- and biocatalysis improved the catalytic yield more than two times compared with that of sole metal catalysis.you can check my other blog about 5428-54-6, you can contact me at any time and look forward to more communication. Synthetic Route of 5428-54-6.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem