Recently I am researching about SODIUM DIISOPROPYLAMIDE; TETRAHYDROFURAN SELECTIVITIES; CONJUGATE ADDITIONS; ARYL DERIVATIVES; ALKALI-METALS; STRONG BASES; VINYL; 2,2,6,6-TETRAMETHYLPIPERIDIDE; LITHIUM; ALKYL, Saw an article supported by the German Academic Scholarship Foundation; DFGGerman Research Foundation (DFG)European Commission; LMU; Projekt DEAL. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Harenberg, JH; Weidmann, N; Karaghiosoff, K; Knochel, P. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone. Application In Synthesis of Benzophenone
The sodiation of substituted acrylonitriles and alkenyl sulfides in a continuous flow set-up using NaDA (sodium diisopropylamide) in EtNMe2 or NaTMP (sodium 2,2,6,6-tetramethylpiperidide).TMEDA in n-hexane provides sodiated acrylonitriles and alkenyl sulfides, which are subsequently trapped in batch with various electrophiles such as aldehydes, ketones, disulfides and allylic bromides affording functionalized acrylonitriles and alkenyl sulfides. This flow-procedure was successfully extended to other acrylates by using Barbier-type conditions.
Application In Synthesis of Benzophenone. About Benzophenone, If you have any questions, you can contact Harenberg, JH; Weidmann, N; Karaghiosoff, K; Knochel, P or concate me.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem