I found the field of Chemistry very interesting. Saw the article A 2D-layered Cd(II) MOF as an efficient heterogeneous catalyst for the Knoevenagel reaction published in 2021. Recommanded Product: 3-Nitrobenzaldehyde, Reprint Addresses Kurup, MRP (corresponding author), Cent Univ Kerala, Sch Phys Sci, Dept Chem, Kasaragod 671320, Kerala, India.. The CAS is 99-61-6. Through research, I have a further understanding and discovery of 3-Nitrobenzaldehyde
A Cd(II) coordination polymer based on a polytopic compartmental ligand was synthesized, and used as an efficient heterogeneous catalyst for the Knoevenagel reaction between benzaldehyde and malononitrile under mild reaction conditions. The solid catalyst was characterized using single crystal XRD, X-ray powder diffraction, SEM, TGA, UV diffuse reflectance, infrared spectroscopy and elemental analysis. The compound is a two-dimensional (2D) MOF with a grid structure. Topological analysis of the framework revealed that it is a 2,4-connected binodal net. The catalytic activity was tested between various benzaldehydes containing different substituents with malononitrile. The effect of reaction parameters such as solvent, time, reactant ratio and catalyst amount was investigated. Furthermore, the catalyst stability was examined through reusability experiments and it is observed that the catalyst can be recycled at least five times without significant drop in its activity.
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Reference:
Thiomorpholine – Wikipedia,
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