Computed Properties of C10H12O3. McClelland, DJ; Galebach, PH; Motagamwala, AH; Wittrig, AM; Karlen, SD; Buchanan, JS; Dumesic, JA; Huber, GW in [McClelland, Daniel J.; Galebach, Peter H.; Motagamwala, Ali Hussain; Dumesic, James A.; Huber, George W.] Univ Wisconsin, Dept Chem & Biol Engn, Madison, WI 53706 USA; [Motagamwala, Ali Hussain; Karlen, Steven D.; Dumesic, James A.] Wisconsin Energy Inst, Great Lakes Bioenergy Res Ctr, Madison, WI USA; [Wittrig, Ashley M.; Buchanan, J. Scott] ExxonMobil Res & Engn Co, Annandale, NJ USA; [Karlen, Steven D.] Univ Wisconsin, Dept Biochem, 420 Henry Mall, Madison, WI 53705 USA published Supercritical methanol depolymerization and hydrodeoxygenation of lignin and biomass over reduced copper porous metal oxides in 2019, Cited 43. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2.
Supercritical methanol depolymerization and hydrodeoxygenation (SCM-DHDO) of maple wood and lignin extracted with GVL from maple wood, was studied using a copper porous metal oxide catalyst. Phenols (P or H), guaiacols (G), and syringols (S) with deoxygenated 1 to 3-carbon (C-1-C-3) alkyl tails were the early products (15 min reaction time) from both the maple wood and the GVL extracted lignin. Furthermore, at 15 min reaction time, the maple wood products showed increased levels of demethoxylation with an S/G/P ratio of 1.0/4.2/1.2 versus 1.0/1.0/0.1 from the GVL extracted lignin products. After 4 h of reacting lignin monomers, dimers and trimers were produced with both the maple wood and extracted lignin. However, the 4 h maple wood products yielded twice the amount of lignin monomers (43.1%) as compared to the 4 h GVL extracted lignin products (20.1%). The GVL extracted lignin products were in the dimer to trimer molecular weight (MW, similar to 180-750 Da) ranges whereas the maple wood products were in the monomer to dimer MW ranges (similar to 94-500 Da) according to the GPC results. NMR and FT-ICR MS analyses show that both the 4 h maple wood products and 4 h GVL extracted lignin products undergo a high degree of hydrodeoxygenation, saturation, and repolymerization by C-C bond formation. The higher yield of lignin monomers from the maple wood is likely due to the lower lignin concentration that occurs during the reaction whereas higher lignin concentration during the reaction leads to more oligomerization reactions.
Computed Properties of C10H12O3. About 4-Methoxybenzyl acetate, If you have any questions, you can contact McClelland, DJ; Galebach, PH; Motagamwala, AH; Wittrig, AM; Karlen, SD; Buchanan, JS; Dumesic, JA; Huber, GW or concate me.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem