Recommanded Product: 3-Nitrobenzaldehyde. Authors Karimi, B; Ghaffari, B; Vali, H in ACADEMIC PRESS INC ELSEVIER SCIENCE published article about in [Karimi, Babak; Ghaffari, Bahareh] Inst Adv Studies Basic Sci IASBS, Dept Chem, 444 Prof Yousef Sobouti Blvd,POB 45195-1159, Zanjan 4513766731, Iran; [Karimi, Babak] Inst Adv Studies Basic Sci IASBS, Res Ctr Basic Sci & Modern Technol RBST, Zanjan 4513766731, Iran; [Vali, Hojatollah] McGill Univ, Dept Anat & Cell Biol, Montreal, PQ H3A 2A7, Canada; [Vali, Hojatollah] McGill Univ, Facil Electron Microscopy Res, Montreal, PQ H3A 2A7, Canada in 2021.0, Cited 75.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6
Hypothesis: It is expected that incorporation of 2, 2, 6, 6-tetra-methyl piperidine-N-oxyl radical (TEMPO) and an imidazolium bromide bearing hydrophilic triethylene glycol (TEG) groups on Fe3O4@SiO2 core-shell may not only result in a novel highly water-dispersible/magnetically separable multi-functional catalyst system for metal-free aerobic oxidation of alcohols, which operates through a synergistic relay pathway, but it could potentially provide a strong platform for simultaneous separation and recycling of all components. Experiments: The catalyst was prepared by anchoring TEMPO moieties onto a magnetic core-shell Fe3O4@SiO2 functionalized with an ionic liquid bearing TEG groups. The materials was characterized using transmission electron microscopy, Fourier transform infrared spectroscopy, nitrogen adsorption-desorption isotherms, thermal gravimetric analysis, and elemental analysis. The performance of the catalyst was evaluated and quantitatively measured in the aerobic oxidation of alcohols in water. Findings: The catalyst exhibited excellent and stable colloidal dispersion in water and high performance in the aerobic oxidation of various types of alcohols under metal- and halogen-free reaction conditions. As hypothesized, strong synergistic effect between functionalized components was seen in the described reaction. The catalyst displayed excellent dual-adjustable-selectivity in the oxidation of primary alcohols to either the corresponding aldehydes or carboxylic acids by tuning the reaction solvent and/or reaction time and excellent recycling behavior through a double-separation-strategy. (C) 2020 Published by Elsevier Inc.
About 3-Nitrobenzaldehyde, If you have any questions, you can contact Karimi, B; Ghaffari, B; Vali, H or concate me.. Formula: C7H5NO3
Reference:
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