Something interesting about Benzophenone

SDS of cas: 119-61-9. About Benzophenone, If you have any questions, you can contact Gao, C; Xu, J; Zhu, SX; Jian, KX; Xuan, QQ; Song, QL or concate me.

SDS of cas: 119-61-9. Authors Gao, C; Xu, J; Zhu, SX; Jian, KX; Xuan, QQ; Song, QL in ROYAL SOC CHEMISTRY published article about in [Gao, Chao; Xu, Jian; Zhu, Shuxian; Jian, Kaixia; Xuan, Qingqing; Song, Qiuling] Huaqiao Univ, Inst Next Generat Matter Transformat, Coll Chem Engn, 668 Jimei Blvd, Xiamen 361021, Fujian, Peoples R China; [Gao, Chao; Xu, Jian; Zhu, Shuxian; Jian, Kaixia; Xuan, Qingqing; Song, Qiuling] Huaqiao Univ, Coll Mat Sci Engn, 668 Jimei Blvd, Xiamen 361021, Fujian, Peoples R China; [Song, Qiuling] Fuzhou Univ, Univ Coll Chem, Key Lab Mol Synth & Funct Discovery Fujian Prov, Fuzhou 350108, Fujian, Peoples R China; [Song, Qiuling] Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China; [Song, Qiuling] Chinese Acad Sci, Key Lab Organofluorine Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China in 2021.0, Cited 40.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

In the presence of K2S2O8 and HOAc, 3-(2-azidoaryl) substituted propargyl alcohols can go through chemoselective oxidative radical cyclizations to give a pool of anthranils based on Meyer-Schuster rearrangement. It’s proposed that the cyclizations were triggered exclusively by the direct attack of oxygen radicals on the azides. The weak N-O bonds in anthranils could be easily cleaved in the presence of transition metal catalysts and went through aminations with 2-oxo-2-phenylacetic acid and iodobenzene.

SDS of cas: 119-61-9. About Benzophenone, If you have any questions, you can contact Gao, C; Xu, J; Zhu, SX; Jian, KX; Xuan, QQ; Song, QL or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem