An article Aerobic oxidative synthesis of quinazolinones and benzothiazoles in the presence of laccase/DDQ as a bioinspired cooperative catalytic system under mild conditions WOS:000528043700039 published article about ONE-POT SYNTHESIS; HETEROGENEOUS CATALYST; SELECTIVE OXIDATION; C-H; EFFICIENT; DDQ; DERIVATIVES; ALCOHOLS; GREEN; 2-ARYLBENZOTHIAZOLES in [Ghorashi, Nadia; Shokri, Zahra; Moradi, Reza; Rostami, Amin] Univ Kurdistan, Fac Sci, Dept Chem, Sanandaj 6617715175, Iran; [Abdelrasoul, Amira; Rostami, Amin] Univ Saskatchewan, Dept Chem & Biol Engn, 57 Campus Dr, Saskatoon, SK S7N 5A9, Canada in 2020, Cited 53. Recommanded Product: 2-Aminobenzamide. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6
The current study applied laccase/DDQ as a bioinspired cooperative catalytic system for the synthesis of quinazolinones (80-95% yield) and benzothiazoles (65-98% yield) using air or O-2 as ideal oxidants in aqueous media at ambient temperature. The aerobic oxidative cyclization reactions occur in two steps: (i) chemical cyclization; (ii) chemoenzymatic oxidation. These methods are more environment-friendly, efficient, simple and practical than other reported methods due to the use of O-2 as an oxidant, laccase as an eco-friendly biocatalyst, aqueous media as the solvent and free from any toxic transition metal and halide catalysts. Therefore, these methods can be applied in pharmaceutical and other sensitive synthetic procedures.
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