Authors Jurgeleit, R; Grimm-Lebsanft, B; Floser, BM; Teubner, M; Buchenau, S; Senft, L; Hoffmann, J; Naumova, M; Nather, C; Ivanovic-Burmazovic, I; Rubhausen, M; Tuczek, F in WILEY-V C H VERLAG GMBH published article about in [Jurgeleit, Ramona; Floeser, Benedikt Maria; Naether, Christian; Tuczek, Felix] Christian Albrechts Univ Kiel, Inst Inorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany; [Grimm-Lebsanft, Benjamin; Teubner, Melissa; Buchenau, Soren; Ruebhausen, Michael] Univ Hamburg, Ctr Free Electron Laser Sci CFEL, Inst Nanostruktur & Festkcrperphys, Luruper Chaussee 149, D-22761 Hamburg, Germany; [Floeser, Benedikt Maria] Max Planck Inst Chem Energy Convers, Stiftstr 34-36, D-45470 Muhlheim An Der Ruhr, Germany; [Teubner, Melissa] Rhein Westfal TH Aachen, Dept Inorgan Chem, Landoltweg 1, D-52074 Aachen, Germany; [Senft, Laura; Ivanovic-Burmazovic, Ivana] Friedrich Alexander Univ Erlangen Nurnberg, Dept Chem & Pharm, Egerlandstr 1, D-91058 Erlangen, Germany; [Hoffmann, Jonas] Univ Bremen, Inst Analyt & Organ Chem, Leobener Str 7, D-28359 Bremen, Germany; [Hoffmann, Jonas] Univ Bremen, MAPEX, Ctr Mat & Proc, Bibliothekstr 1, D-28359 Bremen, Germany; [Naumova, Maria] Deutsch Elektronen Synchrotron DESY, DESY, Notkestr 85, D-22607 Hamburg, Germany; [Ivanovic-Burmazovic, Ivana] Ludwig Maximilians Univ Munchen, Dept Chem, Butenandtstr 5-13,Haus D, D-81377 Munich, Germany in 2021.0, Cited 71.0. Recommanded Product: 119-61-9. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9
One of the challenges of catalysis is the transformation of inert C-H bonds to useful products. Copper-containing monooxygenases play an important role in this regard. Here we show that low-temperature oxygenation of dinuclear copper(I) complexes leads to unusual tetranuclear, mixed-valent mu(4)-peroxo [Cu-I/Cu-II](2) complexes. These Cu4O2 intermediates promote irreversible and thermally activated O-O bond homolysis, generating Cu2O complexes that catalyze strongly exergonic H-atom abstraction from hydrocarbons, coupled to O-transfer. The Cu2O species can also be produced with N2O, demonstrating their capability for small-molecule activation. The binding and cleavage of O-2 leading to the primary Cu4O2 intermediate and the Cu2O complexes, respectively, is elucidated with a range of solution spectroscopic methods and mass spectrometry. The unique reactivities of these species establish an unprecedented, 100 % atom-economic scenario for the catalytic, copper-mediated monooxygenation of organic substrates, employing both O-atoms of O-2.
About Benzophenone, If you have any questions, you can contact Jurgeleit, R; Grimm-Lebsanft, B; Floser, BM; Teubner, M; Buchenau, S; Senft, L; Hoffmann, J; Naumova, M; Nather, C; Ivanovic-Burmazovic, I; Rubhausen, M; Tuczek, F or concate me.. Recommanded Product: 119-61-9
Reference:
Thiomorpholine – Wikipedia,
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