An article Synthesis of 4-Aryl Pyrrolo[1,2-alpha]quinoxalines via Iron-Catalyzed Oxidative Coupling from an Unactivated Methyl Arene WOS:000661138500008 published article about ONE-POT SYNTHESIS; EFFICIENT SYNTHESIS; ANTIPROLIFERATIVE ACTIVITY; ANTIMALARIAL ACTIVITY; POTENTIAL INHIBITORS; BRONSTED ACID; DERIVATIVES; CLEAVAGE; ACCESS; 1-(2-AMINOPHENYL)-PYRROLES in [Ahn, Jiwon; Lee, Seok Beom; Song, Injae; Chun, Simin; Hong, Suckchang] Seoul Natl Univ, Coll Pharm, Res Inst Pharmaceut Sci, Seoul 08826, South Korea; [Oh, Dong-Chan] Seoul Natl Univ, Coll Pharm, Nat Prod Res Inst, Seoul 08826, South Korea in 2021.0, Cited 48.0. Quality Control of Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9
Herein, we describe the direct synthesis of pyrrolo[1,2-alpha]quinoxaline via oxidative coupling between methyl arene and 1-(2-aminophenyl) pyrroles. Oxidation of the benzylic carbon of the methyl arene was achieved by di-t-butyl peroxide in the presence of an iron catalyst, followed by conversion to an activated aldehyde in situ. Oxygen played a crucial role in the oxidation process to accelerate benzaldehyde formation. Subsequent Pictet-Spengler-type annulation completed the quinoxaline structure. The protocol tolerated various kinds of functional groups and provided 22 4-aryl pyrrolo[1,2-alpha]quinoxalines when various methyl arene derivatives were used. The developed method proceeded in air, and all catalysts, reagents, and solvents were easily accessible.
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Thiomorpholine – Wikipedia,
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