Category: thiomorpholine. Authors Bowser, BH; Wang, S; Kouznetsova, TB; Beech, HK; Olsen, BD; Rubinstein, M; Craig, SL in AMER CHEMICAL SOC published article about in [Bowser, Brandon H.; Wang, Shu; Kouznetsova, Tatiana B.; Beech, Haley K.; Olsen, Bradley D.; Rubinstein, Michael; Craig, Stephen L.] Duke Univ, NSF Ctr Chem Molecularly Optimized Networks, Durham, NC 27708 USA; [Bowser, Brandon H.; Wang, Shu; Kouznetsova, Tatiana B.; Rubinstein, Michael; Craig, Stephen L.] Duke Univ, Dept Chem, Durham, NC 27708 USA; [Beech, Haley K.; Olsen, Bradley D.] MIT, Dept Chem Engn, Cambridge, MA 02139 USA; [Rubinstein, Michael] Duke Univ, Dept Phys, Durham, NC 27708 USA; [Rubinstein, Michael] Duke Univ, Dept Mech Engn & Mat Sci, Durham, NC 27708 USA; [Rubinstein, Michael] Duke Univ, Dept Biomed Engn, Durham, NC 27708 USA; [Rubinstein, Michael] Hokkaido Univ, World Premier Inst Chem React Design & Discovery, Sapporo, Hokkaido, Japan in 2021.0, Cited 50.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9
Mechanochemical reactions that lead to an increase in polymer contour length have the potential to serve as covalent synthetic mimics of the mechanical unfolding of noncovalent stored length domains in structural proteins. Here we report the force-dependent kinetics of stored length release in a family of covalent domain polymers based on cis-1,2-substituted cyclobutane mechanophores. The stored length is determined by the size (n) of a fused ring in an [n.2.0] bicyclic architecture, and it can be made sufficiently large (>3 nm per event) that individual unravelling events are resolved in both constant-velocity and constant-force single-molecule force spectroscopy (SMFS) experiments. Replacing a methylene in the pulling attachment with a phenyl group drops the force necessary to achieve rate constants of 1 s(-1) from ca. 1970 pN (dialkyl handles) to 630 pN (diaryl handles), and the substituent effect is attributed to a combination of electronic stabilization and mechanical leverage effects. In contrast, the kinetics are negligibly perturbed by changes in the amount of stored length. The independent control of unravelling force and extension holds promise as a probe of molecular behavior in polymer networks and for optimizing the behaviors of materials made from covalent domain polymers.
Category: thiomorpholine. About Benzophenone, If you have any questions, you can contact Bowser, BH; Wang, S; Kouznetsova, TB; Beech, HK; Olsen, BD; Rubinstein, M; Craig, SL or concate me.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem