Application In Synthesis of 3-Nitrobenzaldehyde. Hwu, JR; Panja, A; Gupta, NK; Hu, YC; Tan, KT; Lin, CC; Hwang, KC; Hsu, MH; Huang, WC; Tsay, SC in [Hwu, Jih Ru; Panja, Avijit; Gupta, Nitesh K.; Tan, Kui-Thong; Lin, Chun-Cheng; Hwang, Kuo-Chu; Huang, Wen-Chieh; Tsay, Shwu-Chen] Natl Tsing Hua Univ, Dept Chem, Hsinchu 30013, Taiwan; [Hwu, Jih Ru; Panja, Avijit; Gupta, Nitesh K.; Tan, Kui-Thong; Lin, Chun-Cheng; Hwang, Kuo-Chu; Huang, Wen-Chieh; Tsay, Shwu-Chen] Natl Tsing Hua Univ, Frontier Res Ctr Fundamental & Appl Sci Matters, Hsinchu 30013, Taiwan; [Hu, Yu-Chen] Natl Tsing Hua Univ, Dept Chem Engn, Hsinchu 30013, Taiwan; [Hsu, Ming-Hua] Natl Changhua Univ Educ, Dept Chem, Changhua 50007, Changhua, Taiwan published Domino Processes of Arynes Reacting with Three Classes of Nucleophiles for Organic Syntheses in 2021.0, Cited 60.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6.
Synthetic application of arynes is broadened by their reactions with neutral N-, S-, and O-containing nucleophiles to produce three types of compounds. Accordingly, 1,2-dihydroquinolines are synthesized from Schiff bases, alkynes, and arynes through a Diels-Alder reaction. Epoxides are prepared from thioethers and arynes along with aldehydes or ketones through a Johnson-Corey-Chaykovsky reaction. Phenolic ethers are produced from allyl ethers and arynes through a Claisen-type rearrangement. These target molecules, including natural products gamma-asarone, asaricin, and a cholesteryl phenolic ether, are formed through reactions initiated by arynes. These new reactions share a prevailing feature of domino processes, which are carried out in a single flask and afford the desired products in good to high yields.
Application In Synthesis of 3-Nitrobenzaldehyde. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Hwu, JR; Panja, A; Gupta, NK; Hu, YC; Tan, KT; Lin, CC; Hwang, KC; Hsu, MH; Huang, WC; Tsay, SC or concate me.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem