Safety of Benzophenone. Authors Dmitrienko, A; Pilkington, M; Nikonov, GI in WILEY-V C H VERLAG GMBH published article about in [Dmitrienko, Anton; Pilkington, Melanie; Nikonov, Georgii I.] Brock Univ, Dept Chem, 1812 Sir Isaac Brock Way, St Catharines, ON L2S 3A1, Canada in 2021.0, Cited 22.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9
The Al-I compound NacNacAl (1, NacNac = [ArNC(Me)CHC(Me)NAr](-), Ar = 2,6-iPr(2)C(6)H(3)) serves as a template for the chemoselective coupling between carbonyls (benzophenone, fenchone, isophorone, p-tolyl benzoate, N,N-dimethylbenzamide, (1-phenylethylidene)aniline) and pyridine. With the CH-acidic ketone (1R)-(+) camphor, the reaction affords a hydrido alkoxide compound of Al, formed as the result of enolization, whereas an enolizable imine, (1-phenylethylidene)aniline, and the bulky ketone isophorone, still chemoselectively couple with pyridine. In contrast, reaction with the ester p-tolyl benzoate results in cleavage of the ester bond together with replacement of the alkoxy group by a hydrogen atom of the pyridine moiety. This study demonstrates that for carbonyl substrates featuring phenyl substituents, the reaction proceeds via intermediate formation of eta(2)(C,X)-coordinated (X = O, N) carbonyl adducts, whereas the reaction of 1 with (R)-(-)-fenchone in the absence of pyridine leads to CH activation in the pendant isopropyl group of the Ar substituent of the NacNac ligand.
Safety of Benzophenone. About Benzophenone, If you have any questions, you can contact Dmitrienko, A; Pilkington, M; Nikonov, GI or concate me.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem