Authors Ye, JH; Bellotti, P; Paulisch, TO; Daniliuc, CG; Glorius, F in WILEY-V C H VERLAG GMBH published article about in [Ye, Jian-Heng; Bellotti, Peter; Paulisch, Tiffany O.; Daniliuc, Constantin G.; Glorius, Frank] Westfalische Wilhelms Univ Munster, Organ Chem Inst, Corrensstr 40, D-48149 Munster, Germany in 2021.0, Cited 61.0. Product Details of 119-61-9. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9
We report the synthesis of beta-lactams from alpha-ketoacylsilanes and imines, which proceeds via a formal [2+2] photochemical cycloaddition with in situ generation of siloxyketene. This mild and operationally simple reaction proceeds in an atom-economic fashion with broad substrate scope, including aldimines, ketimines, hydrazones, and fused nitrogen heterocycles, affording a variety of important beta-lactams with satisfactory diastereoselectivities in most cases. This reaction also features good functional-group tolerance, facile scalability and product diversification. Experimental and computational studies suggest that alpha-ketoacylsilanes can serve as photochemical precursors by engaging in a 1,3 silicon shift to the distal carbonyl group.
Product Details of 119-61-9. About Benzophenone, If you have any questions, you can contact Ye, JH; Bellotti, P; Paulisch, TO; Daniliuc, CG; Glorius, F or concate me.
Reference:
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