Day: November 2, 2021

Formula: C7H5NO3. Authors Gilanizadeh, M; Zeynizadeh, B in TAYLOR & FRANCIS LTD published article about in [Gilanizadeh, Masumeh; Zeynizadeh, Behzad] Urmia Univ, Fac Chem, Orumiyeh 5756151818, Iran in 2021, Cited 45. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

An efficient green method has been developed for the cascade multi-component Hantzsch reaction of acridinediones and biscoumarins using Fe3O4@SiO2@Ni-Zn-Fe layered double hydroxide (LDH). Nano Ni-Zn-Fe LDH immobilized on silica-layered magnetite was synthesized via a simple co-precipitation procedure, and characterized by scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), X-ray diffraction (XRD) and transmission electron microscopy (TEM). The nanocatalyst has the usual features of Fe3O4@SiO2 and Ni-Zn-Fe LDH. Moreover, it contains magnetism properties which is related to the presence of magnetite in the nanocatalyst and can be easily separated from the reaction mixture with an external magnetic field. Subsequently, the nanomagnetic-LDH was used to evaluate catalytic activity with the tandem synthesis of acridinedione and biscoumarin derivatives. The mesoporous catalyst showed excellent performance for multi-component reactions between aromatic aldehydes, 4-hydroxycoumarin, and dimedone and ammonium acetate. Acridinediones were provided within 15-35 min in 80-96% yields under solvent-free conditions in 70-80 degrees C and also, biscoumarins were obtained within 1-40 min in 87-95% yields under reflux conditions in water. The present study includes noteworthy advantages of mild reaction conditions, short times of reaction, absence of hazardous and expensive organic solvents and reagents, presence of water as an eco-friendly solvent, using green nanomagnetic-LDH and the ability to recycle the nanocatalyst.

Formula: C7H5NO3. About 3-Nitrobenzaldehyde, If you have any questions, you can contact Gilanizadeh, M; Zeynizadeh, B or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Formula: C7H8N2O. In 2019.0 SYNTHESIS-STUTTGART published article about MEDIATED SYNTHESIS; INHIBITORS; FLAVONES; 6-ENDO-DIG; CLOSURE in [Parveen, Iram; Ahmed, Naseem] Indian Inst Technol Roorkee, Dept Chem, Roorkee 247667, Uttar Pradesh, India in 2019.0, Cited 36.0. The Name is 1-Phenylurea. Through research, I have a further understanding and discovery of 64-10-8.

A facile cascade reaction is reported via aza-Michael addition, ring opening, and cyclization between 3-bromoflavone and aniline derivatives or N -phenylurea in the presence of KO t -Bu and CuI in DMF under mild reaction conditions. Products were obtained as stereospecific trans -aminated aurones in good to excellent yields (61-83%). Our protocol is operationally successful with ease, avoids the requirement of additives and ligands, and offers broad substrate scope.

About 1-Phenylurea, If you have any questions, you can contact Parveen, I; Ahmed, N or concate me.. Formula: C7H8N2O

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Quality Control of 2-Aminobenzamide. In 2020 ORG BIOMOL CHEM published article about ACID-CATALYZED TRANSAMIDATION; N-SUBSTITUTED FORMAMIDES; CARBON-DIOXIDE; EFFICIENT SYNTHESIS; AMINES; DERIVATIVES; CARBOXAMIDES; METHANOL; OXIDATION; CO2 in [Huang, Hsin-Yi; Lin, Xiu-Yi; Yen, Shih-Yao; Liang, Chien-Fu] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan in 2020, Cited 91. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6.

N-Formamide synthesis usingN-formyl imide with primary and secondary amines with catalytic amounts ofp-toluenesulfonic acid monohydrate (TsOH center dot H2O) is described. This reaction is performed in water without the use of surfactants. Moreover,N-formyl imide is efficiently synthesized using acylamidines with TsOH center dot H2O in water. In addition,N-formyl imide was successfully used as a carbonyl source in the synthesis of benzimidazole and quinazolinone derivatives. Notable features ofN-formylation of amines by usingN-formyl imide include operational simplicity, oxidant- and metal-free conditions, structurally diverse products, and easy applicability to gram-scale operation.

Quality Control of 2-Aminobenzamide. About 2-Aminobenzamide, If you have any questions, you can contact Huang, HY; Lin, XY; Yen, SY; Liang, CF or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Formula: C13H10O. Authors Sadeghi, K; Seo, J in ELSEVIER published article about in [Sadeghi, Kambiz; Seo, Jongchul] Yonsei Univ, Dept Packaging, 1 Yonseidae Gil, Wonju 26493, Gangwon Do, South Korea in 2021.0, Cited 49.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Herein, the facile photografting coating method was used to develop a novel metal biochelator film by covalent immobilization of citric acid (CA) onto polypropylene (PP) surface. First, PP film underwent a surface modification by UV-grafting of glycidyl methacrylate (GMA) in the presence of benzophenone (BP). The concentrations of GMA (bifunctional monomer) and BP (photoinitiator) were appropriately optimized to achieve the breath-figure-array structure and brush-like grafting configuration with a high availability of the reactive oxirane ring. Subsequently, CA was immobilized onto the PP-g-GMA surface via the ring-opening reaction to obtain the biochelator film (PP-g-GMA-g-CA). Fourier-transform infrared spectroscopy and solid state C-13 nuclear magnetic resonance spectroscopy elucidated the chemical structure and grafting mechanism of grafted samples. X-ray photoelectron spectroscopy was used to detect the chemical composition of the surface of the grafted samples, by which the grafting density was relatively estimated. In addition, the uniformity of the grafting pattern and morphology of the grafting unit were observed using scanning electron microscopy and atomic force microscopy. Furthermore, the carboxylic acid density of the biochelator film (PP-g-GMA-g-CA) was quantified using a toluidine blue O assay, in which approximately 327 +/- 58 nM carboxylic acid was detected per each film. The metal chelating activity of the film was also investigated using the colorimetric ferrozine assay, by which PP-g-GMA-g-CA film chelated approximately 215 +/- 11 nM of Fe3+. Therefore, this newly developed system can be used as a versatile metal biochelator in a wide range of biomedical, cosmetic, and packaging applications.

About Benzophenone, If you have any questions, you can contact Sadeghi, K; Seo, J or concate me.. Formula: C13H10O

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Zhang, XY; Wei, DB; Sun, XF; Bai, CZ; Du, YG in [Zhang, Xinyi; Wei, Dongbin; Sun, Xuefeng; Bai, Chenzhong; Du, Yuguo] Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China; [Zhang, Xinyi; Wei, Dongbin; Sun, Xuefeng; Bai, Chenzhong; Du, Yuguo] Univ Chinese Acad Sci, Beijing 100049, Peoples R China published Free available chlorine initiated Baeyer-Villiger oxidation: A key mechanism for chloroform formation during aqueous chlorination of benzophenone UV filters in 2021, Cited 41. SDS of cas: 119-61-9. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.

Chloroform, a regulated disinfection by-product in water, is often generated during chlorination disinfection treatment. However, the formation of chloroform is heavily dependent on the molecular structures of precursors. Moreover, compounds containing ketone moiety are ubiquitous in water environments. However, it is unclear if they can generate chloroform during chlorination. In this study, 14 benzophenones (BPs), efficient and widely used UV filters, with different substituents were selected to explore chloroform formation during chlorination. All 14 BPs generated chloroform, with yields dependent on their molecular structures and operational conditions. Compounds 2,2′,4,4′-tetrahydroxy-BP and benzophenone produced the highest and lowest chloroform of 0.313 and 0.013 g/g, respectively, corresponding to the fastest and slowest formation rate constants of 1.41 x 10(-1) and 2.71 x 10(-2) min(-1). Alkaline conditions and high chlorine dosages were favorable to chloroform formation. Three reactions played key roles in chloroform formation from BPs: (1) chlorine initiated Baeyer Villiger oxidation converted ketone moieties of BP molecules into esters; (2) the esters further underwent hydrolysis and formed phenolic and benzoic products; and (3) benzoic acids underwent decarboxylation and hydrolysis to form phenolic products. Subsequently, these phenolic products could further generate chloroform in the chlorination system. More importantly, BPs could generate chloroform in the ambient water matrices during practical chlorination treatment. This work emphasized the critical role of Baeyer-Villiger oxidation for chloroform formation, implying that pollutants containing aromatic ketone moieties generate chloroform during chlorination disinfection, and their potential risk should therefore be reviewed. (C) 2020 Elsevier Ltd. All rights reserved.

SDS of cas: 119-61-9. About Benzophenone, If you have any questions, you can contact Zhang, XY; Wei, DB; Sun, XF; Bai, CZ; Du, YG or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

I found the field of Chemistry; Environmental Sciences & Ecology very interesting. Saw the article Titanium-magnesium catalysts for propylene polymerization: Study of interrelations between composition, structure and activity published in 2021.0. Quality Control of Benzophenone, Reprint Addresses Bukatov, GD (corresponding author), Boreskov Inst Catalysis SB RAS, Novosibirsk, Russia.. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone

Propylene polymerization titanium-magnesium catalysts (TMCs) were synthesized from different magnesium compounds with diphenylketone (DPK) as the internal donor. The catalysts differed by an order of magnitude and more in the content of titanium and donor, activity, specific surface area and pore size. Sizes of MgCl2 crystallites with 110 or 104 lateral cuts were calculated from the Ti/Mg and DPK/Mg values. For highly active TMCs the composition, XRD and specific surface area were in agreement with the MgCl2 crystallites with 104 lateral cuts, TiCl4 adsorption on one magnesium ion and elongated in the 001 direction. For low-activity TMCs obtained by reacting Mg with BuCl, the sizes of MgCl2 crystallites in different directions were close. Activity of the catalysts was inversely proportional to the crystallite size calculated from the TMC composition. This dependence was preserved for the catalysts obtained via the substitution of ketone by phthalate.

Quality Control of Benzophenone. About Benzophenone, If you have any questions, you can contact Maslov, DK; Bukatov, GD or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2019 J MASS SPECTROM published article about BOND ACTIVATION; METAL-IONS; DECARBOXYLATION; MECHANISMS in [Piacentino, Elettra L.; Rodriguez, Edwin; Parker, Kevin; Gilbert, Thomas M.; Ryzhov, Victor] Northern Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA; [O’Hair, Richard A. J.] Univ Melbourne, Bio Inst 21, Melbourne, Vic 3010, Australia; [O’Hair, Richard A. J.] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia in 2019, Cited 27. The Name is 4-Methoxybenzyl acetate. Through research, I have a further understanding and discovery of 104-21-2. Computed Properties of C10H12O3

Gas-phase C?C coupling reactions mediated by Ni (II) complexes were studied using a linear quadrupole ion trap mass spectrometer. Ternary nickel cationic carboxylate complexes, [(phen)Ni (OOCR1)](+) (where phen = 1,10-phenanthroline), were formed by electrospray ionization. Upon collision-induced dissociation (CID), they extrude CO2 forming the organometallic cation [(phen)Ni(R-1)](+), which undergoes gas-phase ion-molecule reactions (IMR) with acetate esters CH3COOR2 to yield the acetate complex [(phen)Ni (OOCCH3)](+) and a C?C coupling product R-1-R-2. These Ni(II)/phenanthroline-mediated coupling reactions can be performed with a variety of carbon substituents R-1 and R-2 (sp(3), sp(2), or aromatic), some of them functionalized. Reaction rates do not seem to be strongly dependent on the nature of the substituents, as sp(3)-sp(3) or sp(2)-sp(2) coupling reactions proceed rapidly. Experimental results are supported by density functional theory calculations, which provide insights into the energetics associated with the C?C bond coupling step.

About 4-Methoxybenzyl acetate, If you have any questions, you can contact Piacentino, EL; Rodriguez, E; Parker, K; Gilbert, TM; O’Hair, RAJ; Ryzhov, V or concate me.. Computed Properties of C10H12O3

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Qiao, M; Fu, LJ; Cao, W; Bai, YH; Huang, QX; Zhao, X in SPRINGER HEIDELBERG published article about PAHS; BEHAVIOR in [Qiao, Meng; Fu, Lujing; Cao, Wei; Bai, Yaohui; Zhao, Xu] Chinese Acad Sci, Key Lab Drinking Water Sci & Technol, Res Ctr Ecoenvironm Sci, Beijing 100085, Peoples R China; [Huang, Qiuxin] Minist Ind & Informat Technol, CEPREI Environm Assessment & Monitoring Ctr, Elect Res Inst 5, Guangzhou 510610, Guangdong, Peoples R China; [Zhao, Xu] Univ Chinese Acad Sci, Beijing 100049, Peoples R China in 2019, Cited 28. Computed Properties of C14H10O. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8

Ecological wastewater treatment plant (EWWTP), a kind of emerging wastewater treatment plant (WWTP) in recent years, combined microbiology with botany which is efficient for the removal of nitrogen and organic matter, as well as deodorization. The occurrence and removal of micro-organic pollutants in EWWTPs were still not well known. Polycyclic aromatic hydrocarbons (PAHs) and their typical derivatives (SPAHs) including the oxygenated PAHs (OPAHs), chlorinated PAHs (ClPAHs), and methyl PAHs (MPAHs) were investigated in an EWWTP in Guangdong Province, China. The concentrations of the sigma 6 OPAHs (114-384ng/L) were higher than the sigma 16 PAHs (92-250ng/L), and much higher than the sigma 4 MPAHs (13-64ng/L) and sigma 9 ClPAHs (2-3ng/L) in the EWWTP and the effluent receiving river. The total removal efficiencies of the PAHs, OPAHs, MPAHs, and ClPAHs in the EWWTP (43 +/- 14%, 41 +/- 7%, 55 +/- 16%, and 18 +/- 4%) were lower than the traditional WWTPs, probably due to the lower concentration of the sludge in the ecological treatment. The advanced treatment process (microfiltration and UV disinfection treatment) contributed much less (0-20%) to the whole removal efficiency than the ecological treatment (80-100%). The effluent from the EWWTP slightly reduced the PAHs and SPAHs concentrations in the receiving river. The high concentrations of the PAHs and SPAHs in the receiving river were similar to the influent of the EWWTP, indicating that some untreated wastewater was directly discharged to the river, especially in the upstream.

Computed Properties of C14H10O. About Anthrone, If you have any questions, you can contact Qiao, M; Fu, LJ; Cao, W; Bai, YH; Huang, QX; Zhao, X or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Computed Properties of C14H10O. In 2019 BIOORG MED CHEM LETT published article about ACETYLCHOLINE-RELEASE ENHANCERS; LINOPIRDINE DUP 996; POTASSIUM CURRENTS; KCNQ; DRUG; MODULATORS; MECHANISM; AGENTS in [Porter, Jacob D.; Alsafran, Abdulmohsen; Dockendorff, Chris] Marquette Univ, Dept Chem, POB 1881, Milwaukee, WI 53201 USA; [Vivas, Oscar; Dickson, Eamonn J.] Univ Calif Davis, Dept Physiol & Membrane Biol, 1 Shields Ave, Davis, CA 95616 USA; [Weaver, C. David] Vanderbilt Univ, Vanderbilt Inst Chem Biol, Dept Pharmacol, Nashville, TN 37232 USA; [Weaver, C. David] Vanderbilt Univ, Vanderbilt Inst Chem Biol, Dept Chem, Nashville, TN 37232 USA; [DiMilo, Elliot; Arnold, Leggy A.] Univ Wisconsin, Milwaukee Inst Drug Discovery, Dept Chem & Biochem, Milwaukee, WI 53211 USA in 2019, Cited 34. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8.

A set of novel Kv7.2/7.3 (KCNQ2/3) channel blockers was synthesized to address several liabilities of the known compounds XE991 (metabolic instability and CYP inhibition) and the clinical compound DMP 543 (acid instability, insolubility, and lipophilicity). Using the anthrone scaffold of the prior channel blockers, alternative heteroarylmethyl substituents were installed via enolate alkylation reactions. Incorporation of a pyridazine and a fluorinated pyridine gave an analog (compound 18, JDP-107) with a promising combination of potency (IC50=0.16 mu M in a Kv7.2 thallium flux assay), efficacy in a Kv7.2/7.3 patch clamp assay, and drug-like properties.

About Anthrone, If you have any questions, you can contact Porter, JD; Vivas, O; Weaver, CD; Alsafran, A; DiMilo, E; Arnold, LA; Dickson, EJ; Dockendorff, C or concate me.. Computed Properties of C14H10O

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Ultrahigh Flux and Strong Affinity Poly(N-vinylformamide)-Grafted Polypropylene Membranes for Continuous Removal of Organic Micropollutants from Water WOS:000648552500121 published article about ACID ESTERS PAES; BISPHENOL-A BPA; AQUEOUS-SOLUTION; EFFICIENT REMOVAL; N-VINYLFORMAMIDE; HYDROGEN-BOND; WASTE-WATER; ADSORPTION; POLYMER; TEMPERATURE in [Gui, Qilin; Ouyang, Qi; Zhang, Jinxing; Chen, Xiaonong] Beijing Univ Chem Technol, Beijing Lab Biomed Mat, Beijing 100029, Peoples R China; [Shi, Shuxian] Beijing Univ Chem Technol, Key Lab Carbon Fiber & Funct Polymers, Minist Educ, Beijing 100029, Peoples R China in 2021, Cited 59. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. Computed Properties of C13H10O

The rapid and effective removal of organic micropollutants (OMPs) from water remains a huge challenge for traditional water treatment techniques. Compared with powder adsorbents such as polymers and nanomaterials, the free-standing adsorptive membrane is possible for large-scale applications and shows promise in removing OMPs. Herein, inspired by aquatic plants, a novel free-standing adsorptive membrane (NPPM) with high water flux, strong adsorption affinity, and excellent reproducibility was prepared by one-step UV surface grafting. N-Vinylformamide (NVF) was employed to introduce multiple hydrophilic and hydrogen bonding sites on the surface of commercial polypropylene fiber membranes (PPM). The NPPM exhibits excellent water permeability and ultrahigh water flux (up to 40 000 L/(m(2) h)) and could continuously remove a broad spectrum of OMPs from water. Its adsorption performance is 5-100 times higher than that of PPM and commercial membranes. Even in natural water sources such as tap water and river water, the NPPM shows unchanged adsorption performance and high OMPs removal efficiency (>95%). Notably, the NPPM has excellent regeneration performance and can be regenerated by hot water elution, which provides an environmentally friendly regeneration method without involving any organic solvent. Moreover, the synergy between hydrogen bonding and hydrophobic interaction is revealed, and the hydrophobic interaction provided by the hydrophobic substrate is proved to play a fundamental role in OMPs adsorption. The strong hydrogen bonds between the grafts and the OMPs are demonstrated by variable-temperature FTIR spectroscopy (vt-FTIR), C-13 nuclear magnetic resonance spectroscopy (C-13 NMR), and simulation calculations. The strong hydrogen bonds could increase the enthalpy change and enhance the adsorption affinity, so the NPPM has a strong adsorption affinity, which is 100 times that of similar adsorption membranes. This study not only presents an adsorptive membrane with great commercial potential in the rapid remediation of a water source but also opens a pathway to develop an adsorptive membrane with high water flux and strong adsorption affinity.

Computed Properties of C13H10O. About Benzophenone, If you have any questions, you can contact Gui, QL; Ouyang, Q; Zhang, JX; Shi, SX; Chen, XN or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem